A koala that wandered into my front yard, dazed with heat and dehydrated. I offered him water in the dog's dish (set the dish down and backed away), it took a drink then scarpered up a tree.
A skunk. I was working in an old shed, sitting down sorting through looking for a particular mold. And I looked up and about 5ft in front of me was a little skunk waddling along. Just froze thinking, please don't spray me. It just kept on his merry way and waddled on out.